Introduction to reticular chemistry : metal-organic frameworks and covalent organic frameworks / Omar M. Yaghi, Markus J. Kalmutzki, Christian S. Diercks

By:

Yaghi, Omar M, 1965- [VerfasserIn]

Contributor(s):

Resource type: Ressourcentyp: Buch (Online)Book (Online)Language: English Publisher: Weinheim : Wiley-VCH Verlag GmbH &Co. KGaA, [2019]Copyright date: © 2019Description: 1 Online-Ressource (XXXIX, 509 Seiten)ISBN:

9783527821099
9783527821082
9783527821105

Subject(s):

Additional physical formats: 9783527345021 | Erscheint auch als: Introduction to reticular chemistry. Druck-Ausgabe Weinheim : Wiley-VCH, 2019. xxxix, 509 SeitenRVK: RVK: VH 9700LOC classification:

QD411

DOI: DOI: 10.1002/9783527821099Online resources:

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Summary: Cover -- Title Page -- Copyright -- Contents -- About the Companion Website -- Foreword -- Acknowledgment -- Introduction -- Abbreviations -- Part I Metal‐Organic Frameworks -- Chapter 1 Emergence of Metal‐Organic Frameworks -- 1.1 Introduction -- 1.2 Early Examples of Coordination Solids -- 1.3 Werner Complexes -- 1.4 Hofmann Clathrates -- 1.5 Coordination Networks -- 1.6 Coordination Networks with Charged Linkers -- 1.7 Introduction of Secondary Building Units and Permanent Porosity -- 1.8 Extending MOF Chemistry to 3D Structures -- 1.8.1 Targeted Synthesis of MOF‐5 -- 1.8.2 Structure of MOF‐5 -- 1.8.3 Stability of Framework Structures -- 1.8.4 Activation of MOF‐5 -- 1.8.5 Permanent Porosity of MOF‐5 -- 1.8.6 Architectural Stability of MOF‐5 -- 1.9 Summary -- References -- Chapter 2 Determination and Design of Porosity -- 2.1 Introduction -- 2.2 Porosity in Crystalline Solids -- 2.3 Theory of Gas Adsorption -- 2.3.1 Terms and Definitions -- 2.3.2 Physisorption and Chemisorption -- 2.3.3 Gas Adsorption Isotherms -- 2.3.4 Models Describing Gas Adsorption in Porous Solids -- 2.3.4.1 Langmuir Model -- 2.3.4.2 Brunauer-Emmett-Teller (BET) Model -- 2.3.5 Gravimetric Versus Volumetric Uptake -- 2.4 Porosity in Metal‐Organic Frameworks -- 2.4.1 Deliberate Design of Pore Metrics -- 2.4.2 Ultrahigh Surface Area -- 2.5 Summary -- References -- Chapter 3 Building Units of MOFs -- 3.1 Introduction -- 3.2 Organic Linkers -- 3.2.1 Synthetic Methods for Linker Design -- 3.2.2 Linker Geometries -- 3.2.2.1 Two Points of Extension -- 3.2.2.2 Three Points of Extension -- 3.2.2.3 Four Points of Extension -- 3.2.2.4 Five Points of Extension -- 3.2.2.5 Six Points of Extension -- 3.2.2.6 Eight Points of Extension -- 3.3 Secondary Building Units -- 3.4 Synthetic Routes to Crystalline MOFs -- 3.4.1 Synthesis of MOFs from Divalent Metals.PPN: PPN: 1678478431Package identifier: Produktsigel: ZDB-35-UBC | ZDB-35-WIC

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