Analytical electrogenerated chemiluminescence : from fundamentals to bioassays / edited by Neso Sojic

Contributor(s):

Sojic, Neso [HerausgeberIn]

Resource type: Ressourcentyp: Buch (Online)Book (Online)Language: English Series: RSC detection science series ; 15Publisher: Cambridge : Royal Society of Chemistry, [2020]Copyright date: © 2020Description: 1 Online-Ressource (xiv, 501 Seiten) : Illustrationen, DiagrammeISBN:

9781788015776

Subject(s):

Additional physical formats: 9781788014144 | Erscheint auch als: Analytical Electrogenerated Chemiluminescence : From Fundamentals to Bioassays. Druck-Ausgabe Cambridge : Royal Society of Chemistry, ©2019 | Erscheint auch als: Analytical electrogenerated chemiluminescence. Druck-Ausgabe. London : Royal Society of Chemistry, 2020. xiv, 501 SeitenDDC classification:

541/.35

LOC classification:

QD505.8

DOI: DOI: 10.1039/9781788015776Online resources:

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Summary: Intro; Title; Copyright; Preface; Contents; Chapter 1 Introduction and Overview of Electrogenerated Chemiluminescence; 1.1 Introduction; 1.2 Fundamentals of Electrochemistry and Photophysics for ECL; 1.2.1 Basic Electrochemical Principles; 1.2.2 Basic Photophysical Principles; 1.2.3 Energetics and Kinetics; 1.3 Mechanistic Pathways of ECL; 1.3.1 Electron-transfer Reactions Involving the Luminophore; 1.3.1.1 The Annihilation Pathway; 1.3.1.2 Coreactant Pathway: A Tandem System; 1.3.2 Bond-breaking Reactions Within the Luminophore Frame; 1.3.3 Hot Electron-induced ECLSummary: 1.4 Key Protagonists in the ECL1.4.1 Luminophores; 1.4.2 Coreactants; 1.4.3 Electrode Materials; 1.5 Analytical Applications; 1.5.1 Analytical Strategies; 1.5.2 Bioassays; 1.6 Conclusion; References; Chapter 2 Energetic and Kinetic Aspects of ECL Generation; 2.1 Introduction; 2.2 Energetics of ECL Reactants Annihilation; 2.3 ECL Emission from the Lowest Excited Triplet State; 2.4 ECL Emission from the Lowest Excited Singlet State; 2.5 Concluding Remarks; Acknowledgements; References; Chapter 3 Efficient ECL Luminophores; 3.1 Introduction; 3.2 Inorganic SystemsSummary: 3.2.1 Ru(bpy)32+ and Its Derivatives 3.2.2 Cyclometalated Iridium(iii) Complexes; 3.2.3 Other Metal Complexes; 3.3 Organic Systems; 3.3.1 Polycyclic Aromatic Hydrocarbons (PAHs); 3.3.2 Fluorescent Dyes and their Derivatives; 3.4 Conclusion; References; Chapter 4 Electrochemiluminescence Coreactants; 4.1 Introduction; 4.2 Oxidative-Reduction Coreactants; 4.2.1 Oxalate (C2O42- ) System; 4.2.2 Tri-n-propylamine (TPA); 4.2.3 2-(Dibutylamino)ethanol (DBAE); 4.2.4 Other Amine-related Coreactants; 4.2.4.1 Amino Acids and Peptides; 4.2.4.2 Nucleic Acids; 4.2.4.3 NADHSummary: 4.2.4.4 Alkaloids and Pharmaceuticals4.2.4.5 Pesticides; 4.2.4.6 Amines with Aromatic Diol Group; 4.2.4.7 Hydrazine and Relative Derivatives; 4.2.5 Organic Acids/Alcohols and Relative Derivatives; 4.2.5.1 Pyruvate; 4.2.5.2 Hydroxyl Carboxylic Acid and Related Derivatives; 4.2.5.3 Alcohol; 4.2.5.4 Other Organic Molecules; 4.2.6 QDs; 4.2.7 Sulphite; 4.3 Reductive-Oxidative Coreactants; 4.3.1 Peroxydisulfate; 4.3.2 Oxygen; 4.3.3 Hydrogen Peroxide; 4.4 Conclusions; Acknowledgements; References; Chapter 5 Theoretical Concepts Underlying ECL Generation; 5.1 IntroductionSummary: 5.2 Theory: Mathematical Modelling and Computing5.3 Theory of Transient and Steady-state ECL at Dual Hemi-cylinder Electrode Assemblies; 5.4 Simulations of ECL in Coreactant Systems; 5.5 Theoretical Modelling and Optimization of ECL from Ru2+-doped, Immobilised Silica Nanoparticles; 5.6 Conclusions; Acknowledgements; References; Chapter 6 The Essential Role of Electrode Materials in ECL Applications; 6.1 Introduction; 6.2 Noble Electrode Materials: Platinum and Gold; 6.3 Carbon-based Materials; 6.4 Transparent Electrodes; 6.5 Paper-based Materials and Disposable ElectrodesSummary: 6.6 Boron-doped Diamond (BDD) ElectrodesSummary: Book is ideal for graduate students, academics and researchers in industry looking for a comprehensive guide to the different aspects of electrogenerated chemiluminescencePPN: PPN: 1684665884Package identifier: Produktsigel: ZDB-1-RSEK

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