Functionalization of molecular architectures : advances and applications on low-dimensional compounds / edited by Kazuhiro Shikinaka

Contributor(s):

Shikinaka, Kazuhiro [HerausgeberIn]

Resource type: Ressourcentyp: Buch (Online)Book (Online)Language: English Publisher: Singapore : Pan Stanford Publishing, [2019]Description: 1 Online-RessourceISBN:

9781315150697

Subject(s):

Additional physical formats: 9789814774611. | Erscheint auch als: Functionalization of molecular architectures. Druck-Ausgabe. Singapore : Pan Stanford Publishing, 2019. viii, 164 SeitenLOC classification:

QC611.8.L68

Online resources:

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Summary: 2.5 Kinetics-Dominated Structure of IG-Dicarboxylic Acid Mixtures that Gives Their Thixotropic Nature2.6 Thixotropic Gels Consisting of Imogolite and Ionic Liquid for Application as Quasi-Solid Electrolyte; 2.7 Flow-Orientation of Imogolite in Its Thixotropic Hydrogels; 2.8 Chiral-Linkage-Induced Hierarchical Ordering of Imogolites in Their Thixotropic Gel; 2.9 Robust IG Hydrogels Consisting of Imogolite and Organic Polymers; 2.10 Strain-Induced Reversible Isotropic-Anisotropic Structural Transition of Robust IG Hydrogels; 2.11 Electro-Stimulus Responsive Behavior of IG DispersionSummary: 2.12 Conclusion3. Preparation, Modification, and Hybridization of One-Dimensional Ionic Ladder-Like Polysilsesquioxanes; 3.1 Introduction; 3.2 Preparation of Cationic Ladder-Like Polysilsesquioxanes; 3.2.1 Preparation of Ladder-Like Polysilsesquioxane Containing One Ammonium Group in Each Repeating Unit; 3.2.2 Preparation of Ladder-Like Polysilsesquioxane Containing Two Ammonium Groups in Each Repeating Unit; 3.2.3 Correlation between Catalyst Type and Silsesquioxane Structure; 3.3 Preparation of Anionic Ladder-Like PolysilsesquioxanesSummary: 3.3.1 Preparation of Ladder-Like Polysilsesquioxane Containing Carboxylate Side-Chain Groups3.3.2 Preparation of Ladder-Like Polysilsesquioxane Containing Sulfonate (Sulfo) Side-Chain Groups; 3.4 Modification of Ammonium-Group-Containing Ladder-Like Polysilsesquioxanes; 3.4.1 Preparation of Ladder-Like Polysilsesquioxanes Containing Chiral Side-Chain Groups; 3.4.2 Preparation of Thermostable Ladder-Like Polysilsesquioxanes Containing Hydrophobic Side-Chain Groups; 3.5 Hybridization of Ladder-Like Polysilsesquioxanes; 3.5.1 Hybridization of Chiral Polysilsesquioxanes with Dye CompoundsSummary: 3.5.2 Hybridization of Thermostable Ladder-Like Polysilsesquioxanes with Organic Polymers3.5.3 Hybridization of Ladder-Like Polysilsesquioxane with Carbon Nanotube; 3.6 Conclusion; 4. Dimensionality Transformation of Layered Materials toward the Design of Functional Nanomaterials; 4.1 Introduction; 4.2 Nanoporous Materials (2D to 3D); 4.2.1 Topotactic Conversion of Layered Silicates; 4.2.2 Interlayer Bridging of Layered Silicates into 3D Zeolitic Frameworks; 4.2.3 Functions of 3D Materials Derived from Layered Silicates; 4.2.4 Summary; 4.3 Nanoscrolls (2D to 1D)Summary: Cover; Half Title; Title; Copyrights; Contents; Preface; 1. Low-Dimensional Compounds for Diverse Material Sciences Kazuhiro Shikinaka; 1.1 What Is a Low-Dimensional Compound; 1.2 New Class of Low-Dimensional Compounds that Contribute to Academic/Industrial Fields; 1.3 Conclusions; 2. Stimuli-Responsive Materials Consisting of Rigid Cylindrical Inorganic Low-Dimensional Compound "Imogolite"; 2.1 Introduction; 2.2 Thixotropic Gelation of IGs; 2.3 Structural Transition Process of IG Thixotropic Gel; 2.4 Mechanism of Thixotropic Gelation in IG-Dicarboxylic Acid MixtureSummary: Low-dimensional compounds are molecules that correspond to various shapes, such as rod, ladder (one-dimensional compounds), and sheet (two-dimensional compounds). They are ordinarily found in electromagnetic fields. Recently, versatile low-dimensional compounds were proposed for use as components of various functional materials. These new-class low-dimensional compounds contribute significantly to industrial/materials sciences. The molecular architecture consisting of low-dimensional compounds can also be found in nature. One example is the cell cytoskeleton, which is a network- or bundle-like architecture consisting of rod-like protein assemblies. The cell accomplishes its motility by structural transition of the cytoskeleton—that is, phase transition of the architecture of low-dimensional compounds in response to some stimuli induces shape changes in cells. Another example is nacre, which is composed of layered aragonite platelets, usually a metastable CaCO3 polymorph. The layered inorganic platelets give nacre its stiffness and noncombustibility. Thus, the molecular architecture of low-dimensional compounds in natural life contributes to their functionality. This book reviews various advanced studies on the application of low-dimensional compounds and is, therefore, important for the development of materials sciences and industrial technologiesPPN: PPN: 1685659454Package identifier: Produktsigel: BSZ-4-NLEBK-KAUB | ZDB-4-NLEBK

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