Organo main group chemistry / Kin-ya Akiba

Von:

Akiba, Kin'ya, 1936- [aut]

Resource type: Ressourcentyp: Buch (Online)Buch (Online)Sprache: Englisch Verlag: Hoboken, N.J : Wiley, c2011Auflage: Online-AusgBeschreibung: Online-Ressource (1 online resource (xi, 275 p.)) : illISBN:

9781283227896
1283227894
9781118025871

Schlagwörter:

Andere physische Formen: 0470450339 | 9781118025871 | 9780470450338 | 128322786X | Erscheint auch als: Organo main group chemistry. Druck-Ausgabe Hoboken, New Jersey : Wiley, 2011. xi, 275 SeitenDDC-Klassifikation:

547
SCI013040

RVK: RVK: VK 5500LOC-Klassifikation:

QD251.3

Online-Ressourcen:

Zugang im Netz des KIT

Zusammenfassung: Intro -- ORGANO MAIN GROUP CHEMISTRY -- CONTENTS -- Preface -- 1 Main Group Elements and Heteroatoms: Scope and Characteristics -- 1.1 Aufbau Principle and Sign of Orbitals -- 1.2 Electronic Configuration of an Atom: Main Group Elements and Heteroatoms -- 1.3 Fundamental Properties of Main Group Elements -- 1.4 Acidity of Carboxylic Acid and Substituent Effect -- 1.5 Heteroatom Effect -- 1.5.1 Stabilization of α-Carbocation by Resonance: Stereoelectronic Effect -- 1.5.2 Coordination with Lewis Acids -- References -- Notes 1: Electronegativity -- Notes 2: Importance of Formal Logic-I: Oxidation Number and Formal Charge -- Notes 3: Importance of Formal Logic-II: Octet Rule, Eighteen-Electron Rule, Hypervalence -- 2 Main Group Element Effect -- 2.1 What Is Main Group Element Effect? -- 2.2 Single Bond Energy and π -Bond Energy -- 2.3 Hypervalent Compound -- 2.4 Effect of Hypervalent Bond (1): 3c.4e Bond and Structure -- 2.5 Effect of Hypervalent Bond (2): Apicophilicity and Pseudorotation -- 2.6 Effect of Hypervalent Bond (3): Ligand Coupling Reaction (LCR) and Edge Inversion -- 2.7 Effect of σX-C -- 2.8 Effect of σ.X -C -- Notes 4: (σ, σ*) and (π, π*): HMO (Hueckel Molecular Orbital) and Electrocyclic Reaction -- 3 Lithium, Magnesium, and Copper Compounds -- 3.1 Synthesis -- 3.2 Structure -- 3.3 Reaction -- 3.3.1 Deprotonation as Base -- 3.3.2 Nucleophilic Reaction -- 3.3.3 Conjugate Addition of Lithium Dimethylcuprate -- References -- 4 Boron and Aluminum Compounds -- 4.1 Synthesis -- 4.2 Structure -- 4.3 Reaction -- References -- 5 Silicon, Tin, and Lead Compounds -- 5.1 Synthesis -- 5.2 Reaction -- 5.3 Organotin and Lead Compounds -- References -- Notes 5: Stable Carbene and Its Complex -- 6 Phosphorus, Antimony, and Bismuth Compounds -- 6.1 Phosphorus Compounds -- 6.2 Synthesis of Organophosphorus Compounds.PPN: PPN: 807342254Package identifier: Produktsigel: ZDB-26-MYL | ZDB-30-PAD | ZDB-30-PQE

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