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Carbon-centered free radicals and radical cations : structure, reactivity, and dynamics / edited by Malcolm D.E. Forbes

Contributor(s): Resource type: Ressourcentyp: Buch (Online)Book (Online)Language: English Series: Wiley series on reactive intermediates in chemistry and biology ; 3Publisher: Hoboken, N.J : John Wiley, c2010Edition: Online-AusgDescription: Online-Ressource (1 online resource (xxii, 370 p.)) : illISBN:
  • 9781282490888
  • 1282490885
  • 9780470584101
Subject(s): Additional physical formats: 9780470390092 | 1282486853 | Erscheint auch als: Carbon-centered free radicals and radical cations. Druck-Ausgabe. Hoboken, NJ : Wiley, 2010. XXII, 370 S.DDC classification:
  • 547/.1224 22
  • 547.1224
RVK: RVK: VK 7000LOC classification:
  • QD471
Online resources: Summary: MALCOLM D. E. FORBES, PhD, is Professor of Chemistry at the University of North Carolina at Chapel Hill, where he has served in various capacities since 1990. Professor Forbes's group is involved in free radical research and electron paramagnetic resonance spectroscopy. He is a renowned educator and lecturer and has received numerous awards for his research and teaching methods, including the Sir Harold Thomson Award from Elsevier, a Japan Society for the Promotion of Science Foreign Fellowship Award, a National Science Foundation Young Investigator Award, and the Bernard Smaller Prize for Research in Magnetic Resonance. In 2008, he was a J. W. Fulbright Senior Scholar, living and working in Novosibirsk, Russia.Summary: CARBON-CENTERED FREE RADICALS AND RADICAL CATIONS -- CONTENTS -- About the Volume Editor -- Preface to Series -- Introduction -- Contributors -- 1. A Brief History of Carbon Radicals -- 2. Intermolecular Radical Additions to Alkynes: Cascade-Type Radical Cyclizations -- 2.1 Introduction -- 2.2 Cascade Reactions Involving Radicals of Second Row Elements -- 2.2.1 Cascade Reactions Initiated by Addition of C-Centered Radicals to Alkynes -- 2.2.2 Cascade Reactions Initiated by Addition of O-Centered Radicals to Alkynes (Self-Terminating Radical Oxygenations) -- 2.2.3 Cascade Reactions Initiated by Addition of N-Centered Radicals to Alkynes -- 2.3 Cascade Reactions Initiated by Addition of Higher Main Group (VI)-Centered Radicals to Alkynes -- 2.3.1 Cascade Reactions Initiated by Addition of Sn-Centered Radicals to Alkynes -- 2.4 Cascade Reactions Initiated by Addition of Higher Main Group (VI)-Centered Radicals to Alkynes -- 2.4.1 Cascade Reactions Initiated by Addition of S-Centered Radicals to Alkynes -- 2.4.2 Cascade Reactions Initiated by Addition of Se-Centered Radicals to Alkynes -- 2.5 Cascade Reactions Initiated by Addition of Higher Main Group (V)-Centered Radicals to Alkynes -- 2.5.1 Cascade Reactions Initiated by Addition of P-Centered Radicals to Alkynes -- 3. Radical Cation Fragmentation Reactions in Organic Synthesis -- 3.1 Introduction -- 3.1.1 Oxidative Carbon-Carbon Bond Cleavage -- 3.1.2 Thermodynamic and Kinetic Considerations -- 3.1.3 Reactive Intermediate Lifetime -- 3.2 Electron Transfer-Initiated Cyclization Reactions -- 3.2.1 Rate Enhancement and Mechanistic Studies -- 3.2.2 Development of a Catalytic Aerobic Protocol -- 3.2.3 Oxidative Cascade Reactions -- 3.3 Oxidative Acyliminium Ion Formation -- 3.4 Carbon-Carbon Bond Formation -- 3.4.1 Chemoselectivity and Reactivity -- 3.4.2 Reaction Scope -- 3.5 Summary and Outlook.PPN: PPN: 808807668Package identifier: Produktsigel: ZDB-26-MYL | ZDB-30-PAD | ZDB-30-PQE
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