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Introduction to industrial polyethylene : properties, catalysts, processes / Dennis B. Malpass

By: Resource type: Ressourcentyp: Buch (Online)Book (Online)Language: English Series: Wiley-Scrivener Series ; v.19Publisher: Salem, MA ; Hoboken, N.J : Scrivener, c2010Edition: Online-AusgDescription: Online-Ressource (1 online resource (xvii, 133 p.)) : illISBN:
  • 9781282708112
  • 1282708112
  • 9780470900451
Subject(s): Additional physical formats: 0470625988 | 9780470625989 | Druckausg.: 978-0-470-62598-9 DDC classification:
  • 668.4234
LOC classification:
  • TP1180.P65
Online resources: Summary: Intro -- Introduction to Industrial Polyethylene -- Contents -- Preface -- List of Tables -- List of Figures -- Chapter 1 Introduction to Polymers of Ethylene -- 1.1 Genesis of Polyethylene -- 1.2 Basic Description of Polyethylene -- 1.3 Types and Nomenclature of Polyethylenes -- 1.4 Molecular Weight of Polyethylenes -- 1.5 Transition Metal Catalysts for Ethylene Polymerization -- Chapter 2 Free Radical Polymerization of Ethylene -- 2.1 Introduction -- 2.2 Free Radical Polymerization of Ethylene -- 2.3 Organic Peroxide Initiators -- Chapter 3 Ziegler-Natta Catalysts -- 3.1 A Brief History of Ziegler-Natta Catalysts -- 3.2 Definitions and Nomenclature -- 3.3 Characteristics of Ziegler-Natta Catalysts -- 3.4 Early Commercial Ziegler-Natta Catalysts -- 3.5 Supported Ziegler-Natta Catalysts -- 3.6 Prepolymerized Ziegler-Natta Catalysts -- 3.7 Mechanism of Ziegler-Natta Polymerization -- Chapter 4 Metal Alkyls in Polyethylene Catalyst Systems -- 4.1 Introduction -- 4.2 Aluminum Alkyls in Ziegler-Natta Catalysts -- 4.2.1 Reducing Agent for the Transition Metal -- 4.2.2 Alkylating Agent for Creation of Active Centers -- 4.2.3 Scavenger of Catalyst Poisons -- 4.2.4 Chain Transfer Agent -- 4.3 Magnesium Alkyls in Ziegler-Natta Catalysts -- 4.3.1 R2Mg for Production of Supports -- 4.3.2 R2Mg as Reducing Agent -- 4.4 Lithium Alkyls -- 4.5 Organoboron Compounds -- 4.6 Zinc Alkyls -- 4.7 Safety and Handling of Metal Alkyls -- Chapter 5 Chromium Catalysts -- 5.1 Chromium Catalysts Supported on Metal Oxides -- 5.2 Basic Chemistry of Phillips Catalysts -- 5.3 Generations of Phillips Catalysts -- 5.4 Union Carbide Chromium Catalysts -- 5.5 Mechanism of Polymerization with Supported Chromium Catalysts -- Chapter 6 Single Site Catalysts -- 6.1 Introduction -- 6.2 Metallocene Single Site Catalysts -- 6.2.1 Non-metallocene Single Site Catalysts.PPN: PPN: 808959905Package identifier: Produktsigel: ZDB-26-MYL | ZDB-30-PAD | ZDB-30-PQE | BSZ-30-PQE-K1DLR
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