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Physical properties of macromolecules / Laurence A Belfiore
Resource type: Ressourcentyp: Buch (Online)Buch (Online)Sprache: Englisch Verlag: Hoboken, N.J : Wiley, c2010Auflage: Online-AusgBeschreibung: Online-Ressource (1 online resource (xx, 801 p.)) : illISBN:- 9781282883413
- 1282883410
- 9780470551585
- 9780470228937
- 547.7045
- QC173.4.P65
Inhalte:
Zusammenfassung: LARRY BELFIORE, PhD, is a professor of chemical engineering in the department of chemical and biological engineering at Colorado State University. He has written seventy refereed journal publications, seven book chapters, thirty-four proceedings, and has presented more than one hundred lectures at national and international symposia. He is the author of Transport Phenomena for Chemical Reactor Design, published by Wiley.Zusammenfassung: Intro -- Physical Properties of Macromolecules -- Contents -- Preface -- Part One Glass Transitions in Amorphous Polymers -- 1. Glass Transitions in Amorphous Polymers: Basic Concepts -- 1.1 Phase Transitions in Amorphous Materials -- 1.2 Volume-Temperature and Enthalpy-Temperature Relations in the Vicinity of First-Order and Second-Order Phase Transitions: Discontinuous Thermophysical Properties at T(m) and T(g) -- 1.3 The Equilibrium Glassy State -- 1.4 Physical Aging, Densification, and Volume and Enthalpy Relaxation -- 1.5 Temperature-Pressure Differential Phase Equilibrium Relations for First-Order Processes: The Clapeyron Equation -- 1.6 Temperature-Pressure Differential Phase Equilibrium Relations for Second-Order Processes: The Ehrenfest Equations -- 1.7 Compositional Dependence of T(g) via Entropy Continuity -- 1.8 Compositional Dependence of T(g) via Volume Continuity -- 1.9 Linear Least Squares Analysis of the Gordon-Taylor Equation and Other T(g)-Composition Relations for Binary Mixtures -- 1.10 Free Volume Concepts -- 1.11 Temperature Dependence of Fractional Free Volume -- 1.12 Compositional Dependence of Fractional Free Volume and Plasticizer Efficiency for Binary Mixtures -- 1.13 Fractional Free Volume Analysis of Multicomponent Mixtures: Compositional Dependence of the Glass TransitionTemperature -- 1.14 Molecular Weight Dependence of Fractional Free Volume -- 1.15 Experimental Design to Test the Molecular Weight Dependence of Fractional Free Volume and T(g) -- 1.16 Pressure Dependence of Fractional Free Volume -- 1.17 Effect of Particle Size or Film Thickness on the Glass Transition Temperature -- 1.18 Effect of the Glass Transition on Surface Tension -- References -- Problems -- 2. Diffusion in Amorphous Polymers Near the Glass Transition Temperature -- 2.1 Diffusion on a Lattice.PPN: PPN: 809137151Package identifier: Produktsigel: ZDB-26-MYL | ZDB-30-PAD | ZDB-30-PQE | ZDB-38-EAC | ZDB-38-EBR
pt. 1. Glass transitions in amorphous polymers -- pt. 2. Semicrystalline polymers and melting transitions -- pt. 3. Mechanical properties of linear and crosslinked polymers -- pt. 4. Solid state dynamics of polymeric materials.
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