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Terpyridine-based materials : for catalytic, optoelectronic and life science applications / Ulrich S. Schubert, Andreas Winter and George R. Newkome
Contributor(s): Resource type: Ressourcentyp: Buch (Online)Book (Online)Language: English Publisher: Hoboken : John Wiley & Sons, c2011Edition: Online-AusgDescription: Online-Ressource (1 online resource (xix, 522 p.)) : illISBN:- 9781283370578
- 1283370573
- 9783527639649
- 9783527330386
- 620.1
- 547.593
- QD401
- QD1
Contents:
Summary: In recent years, the utilization of terpyridines both in macromolecular structure assembly and device chemistry has exploded, enabling, for example, supramolecular polymer architectures with switchable chemical and physical properties as well as novel functional materials for optoelectronic applications such as light-emitting diodes and solar cells. Further applications include the usage of terpyridines and their metal complexes as catalysts for asymmetric organic reactions and, in a biological context, as anti-tumor agents or biolabels. This book covers terpyridine-based materials topics ranging from syntheses, chemistry, and multinuclear metal complexes, right up to functionalized polymers, 3D-architectures, and surfaces. Aimed at materials scientists, (in)organic chemists, polymer chemists, complex chemists, physical chemists, biochemists, and libraries.Summary: Intro -- Terpyridine-based Materials: For Catalytic, Optoelectronic and Life Science Applications -- Contents -- Preface -- List of Abbreviations -- 1: Introduction -- 2: Synthesis, Properties, and Applications of Functionalized 2,2′:6′,2″-Terpyridines -- 2.1: Introduction -- 2.2: Basic Synthetic Strategies -- 2.2.1: Ring-Assembly Methodologies -- 2.2.2: Cross-Coupling Procedures -- 2.3: Synthesis and Properties of 2,2′:6′,2″-Terpyridine Derivatives -- 2.3.1: 4′-Substituted 2,2′:6′,2″-Terpyridinoxy Derivatives -- 2.3.2: Miscellaneous 4′-Substituted 2,2′:6′,2″-Terpyridine Derivatives -- 2.4: 2,2′:6′,2″-Terpyridines Symmetrically Substituted on the Outer Pyridine Rings -- 2.5: Ziessel-Type 2,2′:6′,2″-Terpyridines -- 2.6: Kröhnke-Type 2,2′:6′,2″-Terpyridines -- 2.7: Miscellaneous Terpyridine-Analogous Compounds -- 2.7.1: Rigid U- and S-Shaped Terpyridines -- 2.7.2: Five-Membered N-Heterocycles Replacing the Outer Pyridine Rings -- 2.7.3: The Swedish Concept: Expanded Bite Angles in Tridentate Ligands -- 3: Chemistry and Properties of Terpyridine Transition Metal Ion Complexes -- 3.1: Introduction -- 3.2: Basic Synthetic Strategies and Characterization Tools -- 3.3: RuII and OsII Complexes -- 3.3.1: Synthesis of RuII and OsII Bis(terpyridine) Complexes -- 3.3.2: RuII Ions and Terpyridine Ligands - A Happy Marriage? -- 3.3.2.1: Photophysical Properties -- 3.3.2.2: Mononuclear RuII Bis(terpyridine) Complexes -- 3.3.2.3: Oligonuclear Complexes Containing RuII/OsII Bis(terpyridine) Units -- 3.3.2.4: Dendritic and Star-Shaped Systems Containing RuII Bis(terpyridine) Units -- 3.4: Iridium(III) Complexes with Terpyridine Ligands -- 3.5: Platinum(II) Mono(terpyridine) Complexes -- 4: Metallo-Supramolecular Architectures Based on Terpyridine Complexes -- 4.1: Introduction -- 4.2: Terpyridine-Containing Metallo-Macrocycles -- 4.3: The HETTAP Concept.PPN: PPN: 809489104Package identifier: Produktsigel: ZDB-26-MYL | ZDB-30-PAD | ZDB-30-PQE
Terpyridine-based Materials: For Catalytic, Optoelectronic and Life Science Applications; Contents; Preface; List of Abbreviations; 1: Introduction; 2: Synthesis, Properties, and Applications of Functionalized 2,2':6',2?-Terpyridines; 2.1: Introduction; 2.2: Basic Synthetic Strategies; 2.2.1: Ring-Assembly Methodologies; 2.2.2: Cross-Coupling Procedures; 2.3: Synthesis and Properties of 2,2':6',2?-Terpyridine Derivatives; 2.3.1: 4'-Substituted 2,2':6',2?-Terpyridinoxy Derivatives; 2.3.2: Miscellaneous 4'-Substituted 2,2':6',2?-Terpyridine Derivatives
2.4: 2,2':6',2?-Terpyridines Symmetrically Substituted on the Outer Pyridine Rings2.5: Ziessel-Type 2,2':6',2?-Terpyridines; 2.6: Kröhnke-Type 2,2':6',2?-Terpyridines; 2.7: Miscellaneous Terpyridine-Analogous Compounds; 2.7.1: Rigid U- and S-Shaped Terpyridines; 2.7.2: Five-Membered N-Heterocycles Replacing the Outer Pyridine Rings; 2.7.3: The Swedish Concept: Expanded Bite Angles in Tridentate Ligands; 3: Chemistry and Properties of Terpyridine Transition Metal Ion Complexes; 3.1: Introduction; 3.2: Basic Synthetic Strategies and Characterization Tools; 3.3: RuII and OsII Complexes
Terpyridine-based Materials: For Catalytic, Optoelectronic and Life Science Applications; Contents; Preface; List of Abbreviations; 1: Introduction; 2: Synthesis, Properties, and Applications of Functionalized 2,2′:6′,2″-Terpyridines; 2.1: Introduction; 2.2: Basic Synthetic Strategies; 2.2.1: Ring-Assembly Methodologies; 2.2.2: Cross-Coupling Procedures; 2.3: Synthesis and Properties of 2,2′:6′,2″-Terpyridine Derivatives; 2.3.1: 4′-Substituted 2,2′:6′,2″-Terpyridinoxy Derivatives; 2.3.2: Miscellaneous 4′-Substituted 2,2′:6′,2″-Terpyridine Derivatives
2.4: 2,2′:6′,2″-Terpyridines Symmetrically Substituted on the Outer Pyridine Rings2.5: Ziessel-Type 2,2′:6′,2″-Terpyridines; 2.6: Kröhnke-Type 2,2′:6′,2″-Terpyridines; 2.7: Miscellaneous Terpyridine-Analogous Compounds; 2.7.1: Rigid U- and S-Shaped Terpyridines; 2.7.2: Five-Membered N-Heterocycles Replacing the Outer Pyridine Rings; 2.7.3: The Swedish Concept: Expanded Bite Angles in Tridentate Ligands; 3: Chemistry and Properties of Terpyridine Transition Metal Ion Complexes; 3.1: Introduction; 3.2: Basic Synthetic Strategies and Characterization Tools; 3.3: RuII and OsII Complexes
3.3.1: Synthesis of RuII and OsII Bis(terpyridine) Complexes3.3.2: RuII Ions and Terpyridine Ligands - A Happy Marriage?; 3.3.2.1: Photophysical Properties; 3.3.2.2: Mononuclear RuII Bis(terpyridine) Complexes; 3.3.2.3: Oligonuclear Complexes Containing RuII/OsII Bis(terpyridine) Units; 3.3.2.4: Dendritic and Star-Shaped Systems Containing RuII Bis(terpyridine) Units; 3.4: Iridium(III) Complexes with Terpyridine Ligands; 3.5: Platinum(II) Mono(terpyridine) Complexes; 4: Metallo-Supramolecular Architectures Based on Terpyridine Complexes; 4.1: Introduction
4.2: Terpyridine-Containing Metallo-Macrocycles4.3: The HETTAP Concept; 4.4: Racks and Grids; 4.5: Helicates; 4.6: Rotaxanes and Catenanes; 4.7: Miscellaneous Structures; 4.7.1: Cyclodextrin Derivatives; 4.7.2: Other Assemblies; 5: C0; -Conjugated Polymers Incorporating Terpyridine Metal Complexes; 5.1: Introduction; 5.2: Metallo-Supramolecular Polymerization; 5.3: Metallopolymers Based on C0; -Conjugated Bis(terpyridine)s; 5.3.1: Polymerization by Transition Metal Ion Coordination; 5.3.2: Self-Assembly of Metallopolymers; 5.3.3: Chiral Metallopolymers; 5.3.4: Non-Classical Metallopolymers
5.3.5: Polymerization Using the ''Complex First'' Method5.4: Main-Chain Metallopolymers Based on Terpyridine-Functionalized C0; -Conjugated Polymers; 6: Functional Polymers Incorporating Terpyridine-Metal Complexes; 6.1: Introduction; 6.2: Polymers with Terpyridine Units in the Side-Chain; 6.2.1: Materials Based on Flexible Organic Polymers; 6.2.2: Materials Based on C0; -Conjugated Polymers; 6.3: Polymers with Terpyridines within the Polymer Backbone; 6.3.1: Polymers from Organic Small-Molecule Building Blocks; 6.3.2: Chain-Extended Polymers from Polymeric Building Blocks
6.3.3: Monotopic Macroligands by End-Group Functionalization
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