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Ionic interactions in natural and synthetic macromolecules / ed. by Alberto Ciferri ...
Contributor(s): Resource type: Ressourcentyp: Buch (Online)Book (Online)Language: English Publisher: Hoboken, N.J : Wiley, c2012Edition: Online-AusgDescription: Online-Ressource (1 online resource (xviii, 852 p.)) : ill. (some col.)ISBN:- 9781283409636
- 1283409631
- 9781118165867
- 547/.7045723 23
- 547.7045723
- 547.7
- SCI013030
- QD381
Contents:
Summary: This book is a comprehensive study of the subject of ionic interactions in macromolecules. The first parts of the book review and analyze the conventional treatments of fixed charges (e.g. in polyelectrolytes and polyampholytes), including screening and condensation by mobile ions. The interaction of ions with less polar sites on the macromolecule (e.g. amide bonds), and the origin of the lyotropic effects (focusing on binding versus condensation) will also be extensively addressed. The book also explores complex micellar organizations involving charged macromolecules (e.g. DNA) and low-molecular-weight ampholytes and strong protein associations. The resulting structures are relevant to a variety of functional biological systems and synthetic analogs. The contribution of electrostatic and hydrophobic interaction to the stability of proteins and other supramolecular structures will also be analyzed. There are chapters on applications such as deionization and cosmetic formulation. This 21-chapter book is divided into three sections: Fundamentals Mixed Interactions Functions and Applications.Summary: Intro -- IONIC INTERACTIONS IN NATURAL AND SYNTHETIC MACROMOLECULES -- CONTENTS -- PREFACE -- CONTRIBUTORS -- PART I: FUNDAMENTALS -- 1: ION PROPERTIES -- 2: IONIC INTERACTIONS IN SUPRAMOLECULAR COMPLEXES -- 3: POLYELECTROLYTE FUNDAMENTALS -- 4: POLYELECTROLYTE AND POLYAMPHOLYTE EFFECTS IN SYNTHETIC AND BIOLOGICAL MACROMOLECULES -- 5: MODELING THE STRUCTURE AND DYNAMICS OF POLYELECTROLYTE MULTILAYERS -- PART II: MIXED INTERACTIONS -- 6: IONIC MIXED INTERACTIONS AND HOFMEISTER EFFECTS -- 7: HYDROPHOBIC POLYELECTROLYTES -- 8: ASSOCIATION OF POLYELECTROLYTES TO SURFACTANTS AND SUPRAMOLECULAR ASSEMBLIES: COMPETITIVE ROLE OF CHAIN RIGIDITY AND ASSEMBLY STABILITY -- 9: ION TRANSFER IN AND THROUGH CHARGED MEMBRANES: STRUCTURE, PROPERTIES, AND THEORY -- 10: REVERSIBLE COORDINATION POLYMERS -- 11: STRUCTURAL AND FUNCTIONAL ASPECTS OF METAL BINDING SITES IN NATURAL AND DESIGNED METALLOPROTEINS -- 12: CHARGE-INDUCED EFFECTS ON ACID-BASE TITRATION AND CONFORMATIONAL STABILITY OF PROTEINS AND POLYPEPTIDES -- PART III: FUNCTIONS AND APPLICATIONS -- 13: IRON TRANSPORT IN LIVING CELLS -- 14: DNA-LIPID AMPHIPHILES FOR DRUG AND GENE THERAPY -- 15: POLYELECTROLYTE INTELLIGENT GELS: DESIGN AND APPLICATIONS -- 16: IONIC POLYMER-METAL COMPOSITES FOR SENSORS AND ARTIFICIAL MUSCLES: MECHANOELECTRIC PERSPECTIVES -- 17: FUNCTIONAL LAYER-BY-LAYER POLYELECTROLYTES: ASSEMBLY STRATEGIES, CHARACTERIZATION, AND SELECTED APPLICATIONS -- 18: POLYELECTROLYTES AT INTERFACES: APPLICATIONS AND TRANSPORT PROPERTIES OF POLYELECTROLYTE MULTILAYERS IN MEMBRANES -- 19: SELF-ASSEMBLY OF POLYELECTROLYTES FOR PHOTONIC CRYSTAL APPLICATIONS -- 20: APPLICATIONS OF CHARGED MEMBRANES IN SEPARATION, FUEL CELLS, AND EMERGING PROCESSES -- 21: POLYMER GEL ELECTROLYTES: CONDUCTION MECHANISM AND BATTERY APPLICATIONS -- SYMBOLS -- INDEX.PPN: PPN: 809507862Package identifier: Produktsigel: ZDB-26-MYL | ZDB-30-PAD | ZDB-30-PQE
""Title page""; ""Copyright page""; ""PREFACE""; ""CONTRIBUTORS""; ""PART I: FUNDAMENTALS""; ""CHAPTER 1 ION PROPERTIES""; ""1.1 IONS AS CHARGED PARTICLES""; ""1.2 SIZES OF IONS""; ""1.3 THERMODYNAMICS OF AQUEOUS IONS""; ""1.4 ION TRANSPORT""; ""1.5 IONâ€"SOLVENT INTERACTIONS""; ""1.6 IONâ€"ION INTERACTIONS""; ""CHAPTER 2 IONIC INTERACTIONS IN SUPRAMOLECULAR COMPLEXES""; ""2.1 INTRODUCTION/APPLICATIONS""; ""2.2 SYSTEMS DOMINATED ENTIRELY BY ION PAIRING: IONOPHORES AND SO ON""; ""2.3 ENTHALPIC VERSUS ENTROPIC CONTRIBUTIONS/HYDROGEN BOND CONTRIBUTIONS""
""2.4Â QUANTIFICATION OF SALT BRIDGE CONTRIBUTIONS/ADDITIVITY OF BINDING INCREMENTS""""2.5Â SALT EFFECTS/INFLUENCE OF CONFORMATIONAL FLEXIBILITY""; ""2.6Â SYSTEMS WITH ADDITIONAL INTERACTIONS/ARTIFICIAL RECEPTORS FOR NUCLEOTIDES AND NUCLEOSIDES""; ""2.7Â SELECTIVITY IN COMPLEXES WITH ION PAIR CONTRIBUTION""; ""2.8Â CONCLUSIONS""; ""CHAPTER 3 POLYELECTROLYTE FUNDAMENTALS""; ""3.1Â INTRODUCTION""; ""3.2Â PB EQUATION AND THE DH APPROXIMATION""; ""3.3Â EXTENDED CONDENSATION THEORY""
""3.4Â ATTRACTION AND CLUSTERS OF LIKE-CHARGED STRONG POLYELECTROLYTES IN THE CONDENSATION APPROACH: MONOVALENT COUNTERIONS AND EFFECT OF CONDENSATION VOLUME""""3.5Â ATTRACTION OF LIKE-CHARGED POLYELECTROLYTES FOR MULTIVALENT COUNTERIONS: COUNTERION CORRELATION APPROACH""; ""3.6Â INTERACTIONS BETWEEN POLYELECTROLYTES AND OPPOSITELY CHARGED MACROIONS""; ""CHAPTER 4 POLYELECTROLYTE AND POLYAMPHOLYTE EFFECTS IN SYNTHETIC AND BIOLOGICAL MACROMOLECULES""; ""4.1Â INTRODUCTION""; ""4.2Â PERSISTENCE LENGTH OF PES""; ""4.3Â PAs""; ""4.4Â PAS WITH EXCESS CHARGES""
""4.5Â ELASTIC RESPONSE OF FLEXIBLE PES""""4.6Â SIMULATIONS OF COLLAPSE OF AN ISOLATED PE CHAIN""; ""4.7Â THEORY OF COLLAPSE DYNAMICS""; ""4.8Â CONCLUSIONS""; ""ACKNOWLEDGMENTS""; ""CHAPTER 5 MODELING THE STRUCTURE AND DYNAMICS OF POLYELECTROLYTE MULTILAYERS""; ""5.1Â INTRODUCTION""; ""5.2Â STATE OF THE ART IN THE STUDY OF PEMS""; ""5.3Â THEORETICAL AND ANALYTICAL APPROACHES TO THE MODELING OF PEMS""; ""5.4Â MODELING PEMS VIA NUMERICAL SIMULATIONS""; ""5.5Â TOWARD A BETTER PHYSICAL DESCRIPTION OF PEMS USING NUMERICAL MODELS""; ""5.6Â CHALLENGING TOPICS IN THE NUMERICAL SIMULATIONS OF PEMS""
""5.7Â SUMMARY""""ACKNOWLEDGMENTS""; ""PART II: MIXED INTERACTIONS""; ""CHAPTER 6 IONIC MIXED INTERACTIONS AND HOFMEISTER EFFECTS""; ""6.1Â INTRODUCTION""; ""6.2Â POLYELECTROLYTES""; ""6.3Â ION PAIRING""; ""6.4Â ASSOCIATIONS MEDIATED BY MULTIVALENT MOBILE IONS""; ""6.5Â HYDROPHOBIC POLYELECTROLYTES""; ""6.6Â POLYMERIC IONIC LIQUIDS, POLYMERS-IN-SALT SYSTEMS""; ""6.7Â HOFMEISTER EFFECTS""; ""6.8Â MAIN CONCLUSIONS""; ""ACKNOWLEDGMENTS""; ""CHAPTER 7 HYDROPHOBIC POLYELECTROLYTES""; ""7.1Â INTRODUCTION""; ""7.2Â HYDROPHOBIC AND HYDROPHOBICALLY MODIFIED POLYELECTROLYTES (HPE, HMPE)""
""7.3Â SELF-ASSEMBLY OF HYDROPHOBIC POLYELECTROLYTES""
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