Solvent extraction : classical and novel approaches / Vladimir S. Kislik

By:

Kislik, Vladimir S [aut]

Resource type: Ressourcentyp: Buch (Online)Book (Online)Language: English Publisher: Amsterdam ; Boston : Elsevier, 2012Edition: Online-AusgDescription: Online-Ressource (1 online resource (xv, 555 p.)) : illISBN:

9781280582530
1280582537
9780444537799

Subject(s):

Additional physical formats: 0444537783 | 9780444537799 | 9780444537782 | 1280580887 | Druckausg.: 978-0-444-53778-2 DDC classification:

660/.284248 23
660.284248

LOC classification:

TP156.E8

Online resources:

Zugang im Netz des KIT

Summary: The main challenge in modern solvent extraction separation is that most techniques are mainly empirical, specific and particular for narrow fields of practice and require a large degree of experimentation. This concise and modern book provides a complete overview of both solvent extraction separation techniques and the novel and unified competitive complexation/solvation theory. This novel and unified technique presented in the book provides a key for a preliminary quantitative prediction of suitable extraction systems without experimentation, thus saving researchers time and resources. Analyzes and compares both classical and new competitive models and techniques Offers a novel and unified competitive complexation / solvation theory that permits researchers to standardize some parameters, which decreases the need for experimentation at R&D Presents examples of applications in multiple disciplines such as chemical, biochemical, radiochemical, pharmaceutical and analytical separation Written by an outstanding scientist who is prolific in the field of separation science.Summary: Front Cover -- Solvent Extraction: Classical and Novel Approaches -- Copyright -- Contents -- Preface -- Introduction -- References -- Part I - Conventional (Classical) Principles and Practice of Solvent Extraction -- Chapter 1 - Modern (Classical) Fundamental Principles of Solvent Extraction -- 1. Introduction -- 2. Solvent Extraction By Solvation -- 3. Solvent Extraction with Chemical Reactions (By Complexation) -- 4. Driving Forces of Solvent Extraction -- 5. Influence of Kinetics Factors -- 6. Selectivity -- 7.Factors Affecting Extraction Process -- 8.Module Design Considerations -- 9.Experimental Determination of Distribution Ratios -- 10.Summarizing Remarks -- References -- Chapter 2 - Principles of Solvent Extraction of Organic and Mineral Acids -- 1. Introduction -- 2. Extraction of Acids by Carbon-Bonded Oxygen-Donor Extractants and Substituted Hydrocarbon Solvents -- 3. Phosphorus-bonded Oxygen Donor Extractants -- 4. Aliphatic Amine Extractants -- 5. Extraction of Strong (Inorganic) Acids -- 6. Summarizing Remarks -- References -- Chapter 3 - Chemistry of Metal Solvent Extraction -- 1.Introduction -- 2. Metal Extraction by Cation Exchangers (Acidic Extractants) -- 3 .Metal Extraction by Anion Exchangers (Ion Pair Formation) -- 4. Extraction Through Formation of H-Bonding and Solvating Complexes -- 5. Extraction Through Mixed Complex Formation -- 6. Extractable Complexation of Monovalent Metals -- 7. Extraction with Aqueous Biphasic Systems -- References -- Chapter 4 - Engineering Development of Solvent Extraction Processes -- 1. Introduction -- 2. Extraction Stage -- 3 .Stripping Organic Solutions -- 4 .Extraction Efficiency -- 5 .Equipment Design For Continuous Extraction-Stripping Processes -- 6.Solvent Losses -- 7.Economical Considerations -- 8. Problems With Scale-Up To Industrial Systems -- References.PPN: PPN: 80966447XPackage identifier: Produktsigel: ZDB-26-MYL | ZDB-30-PAD | ZDB-30-PQE | BSZ-30-PQE-K1DLR

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