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Innovative catalysis in organic synthesis : oxidation, hydrogenation, and c-x bond forming reactions / ed. by Pher G. Andersson
Contributor(s): Resource type: Ressourcentyp: Buch (Online)Book (Online)Language: English Publisher: Hoboken : John Wiley & Sons, c2012Edition: Online-AusgDescription: Online-Ressource (1 online resource (xviii, 356 p.)) : illISBN:- 9781280663499
- 1280663499
- 9783527646616
- 9783527330973
- 547.2
- 541
- 541.395
- 541/.395
- QD505
Contents:
Summary: C-H, C-O, C-C, and C-Heteroatom bond forming processes by using metal-ligand approaches for the synthesis of organic compounds of biological, pharmacological and organic nanotechnological utility are the key areas addressed in this book. Authored by a European team of leaders in the field, it brings together innovative approaches for a variety of catalysis reactions and processes frequently applied in organic synthesis into a handy reference work. It covers all major types of catalysis, including homogeneous, heterogeneous, and organocatalysis, as well as mechanistic and computational studies. Special attention is paid to the improvements in efficiency and sustainability of important catalytic processes, such as selective oxidations, hydrogenation, and cross-coupling reactions, and to their utilization in industry. The result is a valuable resource for advanced researchers in both academia and industry, as well as graduate students in organic chemistry aiming for chemo-, regio- or stereoselective synthesis of organic compounds by using novel catalytic systems.Summary: Intro -- Innovative Catalysis in Organic Synthesis -- Contents -- Foreword -- List of Contributors -- Part I Oxidation Reactions -- 1 Polyoxometalates as Homogeneous Oxidation Catalysts -- 1.1 Soluble Metal Oxides as Oxidation Catalysts -- 1.2 Homogeneous Oxidations with POMs Based Only on Mo(VI), W(VI), V(V) Addenda Ions -- 1.2.1 Oxidation with Hydrogen Peroxide by Peroxopolyoxotungstates-Dendrimers -- 1.2.2 Homogeneous Oxidation with Hydrogen Peroxide in the Presence of Vacant and Hybrid POMs -- 1.3 Homogeneous Oxidations with TMS-POMs -- 1.3.1 Peroxopolyoxometalates of Hf/Zr -- 1.3.2 Aerobic Oxidations with Polyoxopalladates -- 1.3.3 TMSPs as Oxygen-Evolving Catalysts -- 1.4 Conclusions -- Acknowledgments -- References -- 2 Bioinspired Oxidations Catalyzed by Nonheme Iron and Manganese Complexes -- 2.1 Introduction -- 2.2 Catalytic Oxidation of C=C Bonds by Nonheme Iron and Manganese Complexes -- 2.2.1 Epoxidation -- 2.2.1.1 Iron-Based Catalysts -- 2.2.1.2 Manganese-Based Catalysts -- 2.2.2 cis-Dihydroxylation -- 2.2.2.1 Iron-Based Catalysts -- 2.2.2.2 Manganese-Based Catalysts -- 2.3 Catalytic Oxidation of C-H Bonds by Nonheme Iron and Manganese Complexes -- 2.3.1 Hydroxylation -- 2.3.1.1 Iron-Based Catalysts -- 2.3.1.2 Manganese-Based Catalysts -- 2.3.2 Desaturation -- 2.3.2.1 Iron-Based Catalysts -- 2.3.2.2 Manganese-Based Catalysts -- References -- 3 The Fabulous Destiny of Sulfenic Acids -- 3.1 Introduction -- 3.2 Synthesis of Stable Sulfenic Acids -- 3.3 Generation of Transient Sulfenic Acids -- 3.4 Reactivity of Sulfenic Acids in the Preparation of Sulfoxides and Unsymmetrical Disulfides -- 3.5 Synthesis of Stable Sulfenate Anions -- 3.6 Generation of Transient Sulfenate Anions Leading to Sulfoxides -- 3.7 Conclusions -- References -- 4 Sustainable Catalytic Oxidations with Peroxides -- 4.1 Introduction.PPN: PPN: 809681722Package identifier: Produktsigel: ZDB-26-MYL | ZDB-30-PAD | ZDB-30-PQE | ZDB-38-EBR
Innovative Catalysis in Organic Synthesis; Contents; Foreword; List of Contributors; Part I Oxidation Reactions; 1 Polyoxometalates as Homogeneous Oxidation Catalysts; 1.1 Soluble Metal Oxides as Oxidation Catalysts; 1.2 Homogeneous Oxidations with POMs Based Only on Mo(VI), W(VI), V(V) Addenda Ions; 1.2.1 Oxidation with Hydrogen Peroxide by Peroxopolyoxotungstates-Dendrimers; 1.2.2 Homogeneous Oxidation with Hydrogen Peroxide in the Presence of Vacant and Hybrid POMs; 1.3 Homogeneous Oxidations with TMS-POMs; 1.3.1 Peroxopolyoxometalates of Hf/Zr
1.3.2 Aerobic Oxidations with Polyoxopalladates1.3.3 TMSPs as Oxygen-Evolving Catalysts; 1.4 Conclusions; Acknowledgments; References; 2 Bioinspired Oxidations Catalyzed by Nonheme Iron and Manganese Complexes; 2.1 Introduction; 2.2 Catalytic Oxidation of C=C Bonds by Nonheme Iron and Manganese Complexes; 2.2.1 Epoxidation; 2.2.1.1 Iron-Based Catalysts; 2.2.1.2 Manganese-Based Catalysts; 2.2.2 cis-Dihydroxylation; 2.2.2.1 Iron-Based Catalysts; 2.2.2.2 Manganese-Based Catalysts; 2.3 Catalytic Oxidation of C-H Bonds by Nonheme Iron and Manganese Complexes; 2.3.1 Hydroxylation
2.3.1.1 Iron-Based Catalysts2.3.1.2 Manganese-Based Catalysts; 2.3.2 Desaturation; 2.3.2.1 Iron-Based Catalysts; 2.3.2.2 Manganese-Based Catalysts; References; 3 The Fabulous Destiny of Sulfenic Acids; 3.1 Introduction; 3.2 Synthesis of Stable Sulfenic Acids; 3.3 Generation of Transient Sulfenic Acids; 3.4 Reactivity of Sulfenic Acids in the Preparation of Sulfoxides and Unsymmetrical Disulfides; 3.5 Synthesis of Stable Sulfenate Anions; 3.6 Generation of Transient Sulfenate Anions Leading to Sulfoxides; 3.7 Conclusions; References; 4 Sustainable Catalytic Oxidations with Peroxides
4.1 Introduction4.2 Metal-Based Selective Oxidations; 4.2.1 Bromination Reactions; 4.2.2 Oxidation of Nitrogen-Containing Substrates; 4.2.3 Oxidation of Sulfur-Containing Substrates; 4.2.4 Oxidation of Alkenes; 4.3 Biocatalytic Oxidations with Hydrogen Peroxide; 4.3.1 Why Enzymes and HOOH?; 4.3.2 Biocatalytic Sulfoxidation; 4.3.3 Biocatalytic Alkenes Epoxidation; 4.3.4 Biocatalytic Alcohols Oxidation; 4.4 Conclusions; Acknowledgments; References; Part II Hydrogenation and Reduction Reactions
5 Asymmetric Hydrogenation of Dehydroamino acid Derivatives by Rh-Catalysts with Chiral Monodentate P-Ligands5.1 Introduction; 5.2 Chiral Monodentate Phosphorus Ligands in Asymmetric Hydrogenation; 5.3 Catalyst Precursors; 5.4 Mechanistic Insights; 5.5 Formation of the MAC Adducts; 5.6 Evolution of MAC-Adducts and Origin of Enantioselection; References; 6 Recent Advances in the Synthesis and Catalytic Hydrogenation of Dehydroamino Acid Derivatives and Bicyclo[2.2.2]octenes; 6.1 Introduction; 6.2 Synthesis of DDAA Derivatives and Bicyclo[2.2.2]octenes; 6.3 Ligands
6.4 Homogeneous Hydrogenation and Hydrogenolysis Reactions with Dehydroamino Acid Derivatives and Bicyclo[2.2.2]oct-7-enes over Nanocolloids-Modified Catalysts
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