Isocyanide chemistry : applications in synthesis and materials science / edited by Valentine Nenajdenko

Mitwirkende(r):

Nenajdenko, Valentin G [oth]

Resource type: Ressourcentyp: Buch (Online)Buch (Online)Sprache: Englisch Verlag: Somerset : John Wiley & Sons, Incorporated, 2012Auflage: Online-AusgBeschreibung: Online-Ressource (1 online resource) : illISBN:

9781283542289
1283542285
9783527652563
9783527652556

Schlagwörter:

Andere physische Formen: 9783527652556 | 9783527652549 | 9783527652532 | 9783527652563 | 9783527330430 | Erscheint auch als: Isocyanide chemistry Druck-Ausgabe | Erscheint auch als: Isocyanide chemistry. Druck-Ausgabe. Weinheim : Wiley-VCH-Verl., 2012. XVIII, 605 S.DDC-Klassifikation:

547.044

RVK: RVK: VK 7400LOC-Klassifikation:

QD412.C15

Online-Ressourcen:

Zugang im Netz des KIT

Zusammenfassung: Intro -- Isocyanide Chemistry: Applications in Synthesis and Material Science -- Contents -- Preface -- List of Contributors -- 1: Chiral Nonracemic Isocyanides -- 1.1 Introduction -- 1.2: Simple Unfunctionalized Isocyanides -- 1.3 Isocyanides Containing Carboxylic, Sulfonyl, or Phosphonyl Groups -- 1.3.1 α-Isocyano Esters -- 1.3.2 α-Isocyano Amides -- 1.3.3 Other Isocyano Esters or Amides -- 1.3.4 Chiral Sulfonylmethyl or Phosphonylmethyl Isocyanides -- 1.4 Isocyanides Containing Amino or Alcoholic Functionalities -- 1.4.1 Chiral Amino or Azido Isocyanides -- 1.4.2 Chiral Hydroxy Isocyanides -- 1.5 Natural Isocyanides -- 1.5.1 Isolation and Natural Sources -- 1.5.2 Synthesis of Naturally Occurring Isocyanides -- 1.6 Isocyanides Used in the Synthesis of Chiral Polyisocyanides -- 1.6.1 Properties -- 1.6.2 Synthesis -- 1.6.3 Applications -- References -- 2: General Aspects of Isocyanide Reactivity -- 2.1 Introduction -- 2.2 Isocyanide-Cyanide Rearrangement -- 2.3 Oxidation/Reduction of the Isocyano Group -- 2.3.1 Oxidation of the Isocyano Group -- 2.3.2 Reactions with Sulfur and Selenium -- 2.3.3 Reduction of the Isocyano Group -- 2.4 Reactions of Isocyanides with Electrophiles -- 2.4.1 Reaction with Acids -- 2.4.2 Reactions with Halogens and Acyl Halides -- 2.4.3 Reactions with Activated Alkenes and Alkynes -- 2.4.4 Reactions with Carbonyl Compounds and Imines -- 2.4.5 Reactions with Activated Heterocumulens -- 2.5 Reactions of Isocyanides with Nucleophiles -- 2.5.1 Reactions with Organometallic Compounds -- 2.5.2 Reactions with Hydroxide, Alcohols, and Amines -- 2.6 Conclusions -- References -- 3: α-Acidic Isocyanides in Multicomponent Chemistry -- 3.1 Introduction -- 3.2 Synthesis of α-Acidic Isocyanides -- 3.3 Reactivity of α-Acidic Isocyanides -- 3.4 MCRs Involving α-Acidic Isocyanides -- 3.4.1 van Leusen Imidazole MCR.PPN: PPN: 80984270XPackage identifier: Produktsigel: ZDB-26-MYL | ZDB-30-PAD | ZDB-30-PQE

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