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Chemical vapor transport reactions / Michael Binnewies ...

Contributor(s): Resource type: Ressourcentyp: Buch (Online)Book (Online)Language: English Original language: German Publisher: Berlin ; Boston : Walter de Gruyter, c2012Edition: Online-AusgDescription: Online-Ressource (1 online resource (614 p.)) : ill. (some col.)ISBN:
  • 9781283627689
  • 128362768X
  • 9783110254655
Subject(s): Additional physical formats: 9783110254655 | 9783110254648 | 1283627663 | Erscheint auch als: Chemical vapor transport reactions. Druck-Ausgabe Berlin : de Gruyter, 2012. xiv, 614, P12 SeitenDDC classification:
  • 541/.39 23
  • 541.39
RVK: RVK: VE 9400LOC classification:
  • QD502.5
Online resources: Summary: This comprehensive handbook covers the diverse aspects of chemical vapor transport reactions from basic research to important practical applications. The book begins with an overview of models for chemical vapor transport reactions and then proceeds to treat the specific chemical transport reactions for the elements, halides, oxides, sulfides, selenides, tellurides, pnictides, among others. Aspects of transport from intermetallic phases, the stability of gas particles, thermodynamic data, modeling software and laboratory techniques are also covered. Selected experiments using chemical vapor transport reactions round out the work, making this book a useful reference for researchers and instructors in solid state and inorganic chemistry.Summary: Intro -- 1 Chemical Vapor Transport Reactions - an Introduction -- 1.1 Historical Development and Principles -- 1.2 Experimental -- 1.3 Thermodynamic Considerations -- 1.4 Equilibrium Solids in Source and Sink -- 1.5 Transport Agent -- 1.6 Overview of Vapor Deposition Methods -- Bibliography -- 2 Chemical Vapor Transport - Models -- 2.1 Thermodynamic Basis for Understanding Chemical Vapor Transport Reactions -- 2.2 Condensed Phases in a Transport Experiment - the Most Simple Case -- 2.3 Complex, Congruent Transports -- 2.4 Incongruent Dissolution and Quasi-stationary Transport Behavior -- 2.4.1 Phase Relations Accompanying Incongruent Dissolution of a Solid -- 2.4.2 The Extended Transport Model -- 2.5 Non-stationary Transport Behavior -- 2.5.1 Chemical Reasons for the Occurrence of Multi-phase Solids -- 2.5.2 The Time Dependence of Chemical Vapor Transport Experiments with Multi-Phase Solids -- 2.5.3 The Model of Co-operative Chemical Vapor Transport -- 2.6 Diffusion, Stoichiometric Flow, and Transport Rate -- 2.6.1 Steady-state Diffusion -- 2.6.2 One-dimensional Steady-state Diffusion as Rate-determining Step -- 2.6.3 The Use of X for the Calculation of Transport Rates of Complex Transport Systems in Closed Ampoules -- 2.6.4 The Use of Solubility X in Open Transport Systems -- 2.6.5 An Example - Calculation of the Transport Rate for the Nickel/Carbon Monoxide System -- 2.7 Diffusion Coefficients -- 2.7.1 The Binary Diffusion Coefficient D0 -- 2.7.2 D0 in Multi-compound Systems -- 2.8 Survey of Gas Motion in Ampoules -- 2.8.1 General Remarks -- 2.8.2 Experiments on Gas Motion - Diffusion and Convection in Closed Ampoules -- 2.8.3 Experiments Concerning Thermal Convection -- 2.9 Chemical Kinetics of Heterogeneous Reactions -- 2.9.1 Reaction Behavior at an Atomic Level -- 2.9.2 Kinetic Influences Observed by Transport Experiments.PPN: PPN: 809902729Package identifier: Produktsigel: ZDB-26-MYL | ZDB-30-PAD | ZDB-30-PQE
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